The weight ranges of 80-105 (Medium) and 90-115 (Large) are weight ranges that the DHV certification was tested at, so for the DHV certification to be valid you must fly the wing within that range (all up weight), but bear in mind the DHV testing was done without a paramotor.
According to: http://www.papteam.com/pap_news_eng.htm
the PAP Motion also has DULV certification at the range 80-140 for the medium and 90-160 for the large, and PAP specify the weight at the higher DULV range, so this is a more useful figure to use.
It is not always best to be at the top end, it depends on the wing and what you want from it, if a manufacturer is specifying a big weight range (like 80-140), I would prefer to be in the middle.
I would recommend taking the trouble to weigh all your gear, and get your all up weight, you need to include everything even the wing that you hav’nt got yet, (the medium PAP Motion should weigh 6.4kg), don’t forget to include some weight for fuel.
If your all up weight is less then 115kg then the medium may be the best choice, if it is more than 115kg the large may be better, but get advise from someone that actually flies them, if you can find anyone!
Paul D